Journal of Organic Chemistry p. 3744 - 3748 (1990)
Update date:2022-09-26
Topics:
Barbaro, G.
Battaglia, A.
Giorgianni, P.
Bonini, B. F.
Maccagnani, G.
Zani, P.
Aromatic and aliphatic, not enethiolizable, thioaldehyde S-oxides (monosubstituted sulfines) are obtained from stereospecific fluorodesilylation of the corresponding thioacylsilane S-oxides with retention of configuration.A detailed investigation on the mechanism of the desilylation, as well as of the acid and fluoride ion induced Z/E interconversion has been performed.
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