LEWIS ACID CATALYZED REARRANGEMENT OF VINYLCYCLOPROPANECARBONYL CHLORIDE TO CYCLOPENTENECARBONYL CHLORIDE

DOI: 10.1246/cl.1986.621

Source and publish data:

Chemistry Letters p. 621 - 624 (1986)

Update date:2022-08-04

Topics:

Authors:

Sakito, Yoji

Suzukamo, Gohfu

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Article abstract of DOI:10.1246/cl.1986.621

Vinylcyclopropane-cyclopentene rearrangement of 2-(2-aryl-vinyl) cyclopropanecarbonyl chlorides was observed upon treatment with a Lewis acid under mild reaction conditions to afford 2-arylcyclopent-3-enecarboxylates after esterification.

Full text of DOI:10.1246/cl.1986.621

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