Diastereoselective Synthesis of β-Methyl-homoallylic Alcohols by lk-Addition of (2-Butenyl)triphenoxytitanium to Aldehydes

DOI: 10.1002/hlca.19820650340

Source and publish data:

Helvetica Chimica Acta p. 1085 - 1089 (1982)

Update date:2022-08-04

Topics:

Authors:

Widler, Leo

Seebach, Dieter

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/hlca.19820650340

(2-Butenyl)triphenoxytitanium, prepared in situ from (2-butenyl)magnesium halogenide and chlorotriphenoxytitanium in tetrahydrofuran solution, adds to aldehydes with like (Re,Re/Si,Si<*>Re*,Re*) relative topicity in diastereoselectivities of 80-99percent.

Full text of DOI:10.1002/hlca.19820650340

Products guided by the article

Product name:(anti)-4-hydroxy-3-methyl-6-phenyl-1-hexene

Cas No:106756-95-0

R&D Labs maybe for 106756-95-0

Lyan Limited

Contact:86-021-52418058

Address:8/F, Building 6, Guiping Road No.333, Shanghai, 200233, China
SHANDONG AONA CHEMICAL CO.,LTD.

Contact:86-532-85762926

Address:LIUYUAN TOWN, ZAOZHUANG CITY, SHANGDONG PROVINCE.
Advanced Biotech

Contact:+1-973-357-0577

Address:10 Taft Rd.
RongCheng Tianyu Technology Co.,Ltd.

Contact:86-631-7519595

Address:220Ping Donghai Road RongChengCity,ShangDong Province China
TIANJIN NORTH JINHENG CHEMICAL PLANT.

Contact:0086-22-59952083

Address:DongShigu Country In JiXian TianJin China

Relevant to this article

Synthesis and Cycloaddition Reactions of Homoadamantano<4,5-c>cyclopentadienones. A Facile Route to <4,5>-Fused Homoadamantanobenzene Derivatives

Doi:10.1021/jo00380a004
(1987)
6-SUBSTITUTED INDOLES FROM o-HALONITROBENZENES

Doi:10.1016/S0040-4039(00)84339-7
(1986)
Short chemical synthesis of (-)-chorismic acid from (-)-shikimic acid

Doi:10.1021/ja00180a039
(1990)
Efficient synthesis and anti-bovine viral diarrhea virus evaluation of 5-(aryldiazo)salicylaldehyde thiosemicarbazone derivatives

Doi:10.1080/00397911.2019.1626893
(2019)
Anticonvulsant O-Alkyl Sulfamates. 2,3:4,5-Bis-O-(1-methylethylidene)-β-D-fructopyranose Sulfamate and Related Compounds.

Doi:10.1021/jm00388a023
(1987)
Reactions between Trimethylenemethane Metal Complexes and the Carbon-Nitrogen Double Bond: Nickel and Palladium catalysed Synthesis of Pyrrolidines

Doi:10.1039/c39860001201
(1986)

Article Doi