Angewandte Chemie - International Edition p. 6473 - 6477 (2008)
Update date:2022-07-29
Topics:
Waldmann, Herbert
Hu, Tai-Shan
Renner, Steffen
Menninger, Sascha
Tannert, Rene
Oda, Toshiro
Arndt, Hans-Dieter
(Chemical Equation Presented) Actin glue: An E-selective ring-closing metathesis as the key step allowed the solid-phase-based total synthesis of the F-actin stabilizer chondramide C as well as the establishment of its hitherto unknown stereochemistry. A strong influence of the polyketide configuration was revealed in cellular assays. Docking studies on the F-actin filament structure led to a detailed model of the binding site.
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