REACTIONS OF METAL CARBONYL CLUSTER COMPLEXES WITH MULTIDENTATE PHOSPHINE LIGANDS; PREPARATION OF BIS(DIPHENYLPHOSPHINO)METHANE DERIVATIVES OF THE TRINUCLEAR COMPLEXES M3(CO)12 (M = Fe, Ru AND Os) AND THE X-RAY CRYSTAL STRUCTURE OF Os3(CO)9(μ-dppm)(Η

Article abstract of DOI:10.1016/0022-328X(86)80105-X

The reaction of bis(diphenylphosphino)methane (dppm) with Fe3(CO)12 gave the known complexes Fe(CO)4(dppm), Fe2(CO7(dppm), in addition to Fe2(CO)5-(dppm)2.Two new dppm derivatives of Ru3(CO)12, Ru3(CO)9(μ-dppm)(η¹-dppm) and Ru3(CO)6(dppm)3 have