Journal of Organic Chemistry p. 1273 - 1276 (1987)
Update date:2022-08-03
Topics:
Kraus, George A.
Molina, Maria Teresa
Walling, John A.
Deoxyfrenolicin and nanaomycin A have been synthesized.Key steps in the synthesis include a phtalide annulation reaction to produce a naphthoquinone, a tandem Diels-Alder/retro-Claisen reaction to produce the carbon skeleton, and a stereoselective reduction of a hemiketal.
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