
Angewandte Chemie - International Edition p. 6999 - 7003 (2008)
Update date:2022-08-06
Topics:
Goldup, Stephen M.
Leigh, David A.
Lusby, Paul J.
McBurney, Roy T.
Slawin, Alexandra M. Z.
(Figure Presented) Gold member: The last of the simple metal coordination geometries (linear) joins the family of metal-ligand arrangements that have been used to template the formation of mechanical bonds. Both catenanes and rotaxanes are assembled about a gold(I) template. The picture shows the molecular structure of the gold(I) catenate, viewed parallel to its N-Au-N bond.
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