Tetrahedron p. 2429 - 2434 (1986)
Update date:2022-08-04
Topics:
Abad, A.
Agullo, C.
Arno, M.
Seoane, E.
Reaction of α-methanesulfonyloxycycloalkanones with KCN in dimethylformamide is examined; this proceeds, with high yield, to give in some cases 1-hydroxybicyclocarbonitriles and in other cases 2-cyanooxiranes.Open chain α-methanesulfonyloxyalkanones afford 2-cyanooxiranes.
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