CLEAVAGE AND REARRANGEMENT OF PHOSPHORUS-CARBON AND PHOSPHINE-METAL BONDS IN ALKYLTRIS(TERTIARY PHOSPHINE)COBALT COMPOUNDS

Article abstract of DOI:10.1016/S0022-328X(00)99664-5

Complexes of the type L3CoCH3 have been prepared in which L=Ph3P, P2PCH3, PhP(CH3)2, Ph2PGe(CH3)3, Ph2PSn(CH3)3, Ph3As, and R=CH3, Ph, and (CH3)3Si.Decomposition of these complexes under mild conditions in several solvents has been studied.Among the ident