STEREOSELECTIVE SYNTHESIS OF Z-DISUBSTITUTED OLEFINS VIA 2,3-SIGMATROPIC REARRANGEMENTS. AN APPROACH TO LEUKOTRIENES.

DOI: 10.1016/S0040-4039(00)84441-X

Source and publish data:

Tetrahedron Letters p. 2033 - 2036 (1986)

Update date:2022-07-31

Topics:

Authors:

Kaye, Aston D.

Pattenden, Gerald

Roberts, Stanley M.

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Article abstract of DOI:10.1016/S0040-4039(00)84441-X

Stereoselective 2,3-sigmatropic rearrangement of the propargyl 2-silylallyl ether(5) leads to the vinyl silane (7), which, after protiodesilylation and palladium catalysed coupling to 3-bromoprop-2-enol, produces the Z,E-dienynol(10) a key intermediate in

Full text of DOI:10.1016/S0040-4039(00)84441-X

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