A NOVEL AND STEREOSELECTIVE SYNTHESIS OF (+/-)-CEPHALOTAXINE AND ITS ANALOGUE

DOI: 10.1016/S0040-4039(00)84438-X

Source and publish data:

Tetrahedron Letters p. 2023 - 2026 (1986)

Update date:2022-09-26

Topics:

Authors:

Yasuda, Shingo

Yamada, Toru

Hanaoka, Miyoji

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)84438-X

Cephalotaxine (1) and its analogue (3) were stereoselectively synthesized from proline via the pyrrolobenzazepine (4) through Claisen rearrangement, cationic cyclization, and regio- and stereo-selective hydroxylation.

Full text of DOI:10.1016/S0040-4039(00)84438-X

Products guided by the article

Product name:1-[2-(3,4-Dimethoxy-phenyl)-acetyl]-pyrrolidine-2-carboxylic acid ethyl ester

Cas No:107672-34-4

R&D Labs maybe for 107672-34-4

SHIJIAZHUANG AGERUO-BIOTECH CO.LTD

Contact:+86-130-2866-6699

Address:Huaian east Road 158
Shenzhen Feiming Science and Technology Co,. Ltd

Contact:+86-755-85232577

Address:#B2309, Fenglin International Center ,Jixiang Road, Longcheng street, LongGang District, Shenzhen city, Guangdong province, China.
Zhejiang Golden-Shell Pharmaceutical Co.,Ltd.

Contact:+86-576-87501888 / 87501988

Address:No.89 Zhongxing Road. Li'ao, Yuhuan, Zhejiang, China
Suzhou Sinosun Imp.&Exp. Corporation

website:http://www.szsinosun.com

Contact:+86-512-63488895,63488616

Address:No.758 East Jiangling Road Wujiang Economic & Technological Developmenty Zone Jiangsu China
Dalian Join King Biochemical Tech. Co., Ltd.

Contact:0411 39216206

Address:814 First State Blvd

Relevant to this article

The synthesis of the metabolites of 21,31,51-Tri-O-acetyl-N6-(3-hydroxyphenyl) adenosine (WS070117)

Doi:10.3390/molecules21010008
(2016)
Reaction of Phenyl-Substituted Allyllithiums with tert-Alkyl Bromides. Remarkable Difference in the Alkylation Regiochemistry between a Polar Process and the One Involving Single-Electron Transfer

Doi:10.1021/ja00245a033
(1987)
Iron-mediated intramolecular metalative cyclization of α,β- unsaturated esters and amides. Versatile one-pot preparation of bicyclic ketoesters

Doi:10.1021/ol802170z
(2008)
Direct formation of β-glycosides of N-acetyl glycosamines mediated by rare earth metal triflates

Doi:10.1039/b807064d
(2008)
A new enantioselective catalytic route to Florhydral

Doi:10.1055/s-2008-1067167
(2008)
Doi:10.1021/jo01373a009
(1954)

Article Doi