TOTAL SYNTHESIS OF (+/-) ASPIDOFRACTININE

DOI: 10.1016/S0040-4039(00)99263-3

Source and publish data:

Tetrahedron Letters p. 3429 - 3432 (1989)

Update date:2022-09-26

Topics:

Authors:

Dufour, Monique

Gramain, Jean-Claude

Husson, Henri-Philippe

Sinibaldi, Marie-Eve

Troin, Yves

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Article abstract of DOI:10.1016/S0040-4039(00)99263-3

The pentacyclic skeleton 10 of the aspidospermine group of indole alkaloids has been constructed from hexahydrocarbazol-4-one 2 with high stereoselectivity.The synthesis of (+/-) 19-oxo aspidofractinine 12, a direct precursor of aspidofractinine 4, illustrates the usefulness of this new general strategy.

Full text of DOI:10.1016/S0040-4039(00)99263-3

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