Infrared, Raman, and visible spectroscopic studies of Zn and Cd matrix reactions with ozone. Spectra of metal ozonides and oxides in solid argon and nitrogen

Article abstract of DOI:10.1063/1.439169

Reactions of zinc and cadmium atoms with ozone during condensation with excess nitrogen or argon produced B⁺O3^- ion-pairs having infrared, Raman, and optical spectra similar to the analogous alkali and alkaline earth metal species.Additional infrared and Raman evidence was found for a different B⁺O3^- ion-pair geometry.Mercury arc photolysis reduced ozonide absorptions and produced new 810 cm^-1 zinc isotopic triplets which showed the appropriate 18O shifts for ZnO, and a new 719 cm^-1 band which showed the proper 18O displacement for CdO.This nitrogen matrix work provides good measures of the yet-to-be-observed gas-phase fundamentals of these high temperature oxides.

Full text of DOI:10.1063/1.439169

Infrared, Raman, and visible spectroscopic studies of Zn and Cd matrix reactions with
ozone. Spectra of metal ozonides and oxides in solid argon and nitrogen
Eleanor S. Prochaska and Lester Andrews
Citation: The Journal of Chemical Physics 72, 6782 (1980); doi: 10.1063/1.439169
View online: http://dx.doi.org/10.1063/1.439169
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/72/12?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
134.153.184.170 On: Thu, 13 Nov 2014 02:37:54

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
134.153.184.170 On: Thu, 13 Nov 2014 02:37:54

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
134.153.184.170 On: Thu, 13 Nov 2014 02:37:54

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
134.153.184.170 On: Thu, 13 Nov 2014 02:37:54

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
134.153.184.170 On: Thu, 13 Nov 2014 02:37:54

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
134.153.184.170 On: Thu, 13 Nov 2014 02:37:54

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
134.153.184.170 On: Thu, 13 Nov 2014 02:37:54

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
134.153.184.170 On: Thu, 13 Nov 2014 02:37:54

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
134.153.184.170 On: Thu, 13 Nov 2014 02:37:54

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
134.153.184.170 On: Thu, 13 Nov 2014 02:37:54