PALLADIUM- OR NICKEL-CATALYZED REACTION OF ALKYNES WITH TRIMETHYLSILYL CYANIDE. A NEW SYNTHESIS OF 5-AMINOPYRROLE-2-CARBONITRILES

DOI: 10.1016/S0040-4039(00)84949-7

Source and publish data:

Tetrahedron Letters p. 4201 - 4204 (1986)

Update date:2022-07-31

Topics:

Authors:

Chatani, Naoto

Hanafusa, Terukiyo

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Article abstract of DOI:10.1016/S0040-4039(00)84949-7

The reaction of alkynes with trimethylsilyl cyanide (1) in the presence of a palladium or nickel catalyst gave 5-aminopyrrole-2-carbonitriles in high yields with high regioselectivity.

Full text of DOI:10.1016/S0040-4039(00)84949-7

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