Journal of Organometallic Chemistry p. 109 - 116 (1986)
Update date:2022-08-02
Topics:
Edelmann, Frank
Behrens, Peter
Behrens, Sabine
Behrens, Ulrich
Tricarbonyl(fulvene)chromium complexes, (C5H4CR2)Cr(CO)3, react with HgCl2 and SnCl4, respectively, to give stable 1:1 adducts.The metal basicity of the tricarbonyl(fulvene)chromium complexes is largely determined by the electronic properties of the substituents R at the exocyclic carbon atom of the fulvene ligand.The first crystalline protonation product of a fulvene complex was obtained by treatment of <η5-6,6-bis(dimethylamino)fulvene>Cr(CO)3 with HBF4.
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(2015)Doi:10.1248/cpb.35.642
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(1986)
