Journal of the Iranian Chemical Society p. 484 - 494 (2011)
Update date:2022-07-29
Topics: Synthesis Catalyst Alcohols Chemoselective Silylation Crystal engineering 18-Crown-6
Zolfigol
Kolvari
Koukabi
Salehzadeh
Chehardoli
Tidmarsh
Niknam
Reaction of 18-crown-6 with KI in ethanol solution followed by addition of iodine (I2) afforded a unique triiodide salt with a nanotube-like structure ({[K.18-Crown-6]I3}n). It is shown that this reagent may be used for the chemoselective trimethylsilylation of alcohols. The synthesis of the crystalline reagent is a good example of crystal engineering. Reagent was recycled and reused.
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