OBSERVATION OF A SILANIMINE IN AN INERT MATRIX AND IN SOLUTION AT LOW TEMPERATURE

DOI: 10.1246/cl.1986.1025

Source and publish data:

Chemistry Letters p. 1025 - 1028 (1986)

Update date:2022-09-26

Topics:

Authors:

Zigler, Steven S.

West, Robert

Michl, Josef

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Article abstract of DOI:10.1246/cl.1986.1025

Irradiation of Mes3SiN3 in 3-methylpentane at 77 K or -140 deg C yields the silanimine, Mes2Si=NMes.The silanimine is yellow (λmax=296, 444 nm) and decomposes at temperatures above ca. -120 deg C.

Full text of DOI:10.1246/cl.1986.1025

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