THE STEREOSELECTIVE MICHAEL REACTION BETWEEN SILYL ENOL ETHERS AND α,β-UNSATURATED KETONES BY THE USE OF TRITYL PERCHLORATE AS A CATALYST

DOI: 10.1246/cl.1986.1017

Source and publish data:

Chemistry Letters p. 1017 - 1020 (1986)

Update date:2022-09-26

Topics: Silyl enol ethers Michael reaction Trityl perchlorate Stereoselective Reaction α,β-Unsaturated Ketones Experimental terms

Authors:

Mukaiyama, Teruaki

Tamura, Masanori

Kobayashi, Shu

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Article abstract of DOI:10.1246/cl.1986.1017

The Michael adducts are obtained with good to excellent ul selectivity by treating silyl enol ethers with α,β-unsaturated ketones in the presence of a catalytic amount of trityl perchlorate.

Full text of DOI:10.1246/cl.1986.1017

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