Efficient Carbonyl Addition of Polyfluorochloroethyl, -ethylidene, and -ethenyl Units by Means of 1,1,1-Trichloro-2,2,2-trifluoroethane and Zinc

DOI: 10.1246/bcsj.60.4377

Source and publish data:

Bulletin of the Chemical Society of Japan p. 4377 - 4384 (1987)

Update date:2022-09-26

Topics:

Authors:

Fujita, Makoto

Hiyama, Tamejiro

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Article abstract of DOI:10.1246/bcsj.60.4377

Thermally stable zinc carbenoid CF3CCl2ZnCl was prepared from 1,1,1-trichloro-2,2,2-trifluoroethane and zinc powder in N,N-dimethylformamide and was allowed to add to carbonyls of aldehydes and α-keto esters in excellent yields to give 1-substituted 2,2-d

Full text of DOI:10.1246/bcsj.60.4377

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