NEW SYNTHESES OF VINYLSILANES AND ALLYLSILANES BY CROSS-COUPLING OF (R3Si)3MnMgMe WITH ALKENYL AND ALLYLIC COMPOUNDS

DOI: 10.1016/S0040-4039(00)84475-5

Source and publish data:

Tetrahedron Letters p. 2161 - 2164 (1986)

Update date:2022-08-03

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Authors:

Fugami, Keigo

Oshima, Koichiro

Utimoto, Kiitiro

Nozaki, Hitosi

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Article abstract of DOI:10.1016/S0040-4039(00)84475-5

The reaction of alkenyl halides, alkenyl sulfides, and enol phosphates with (R3Si)3MnMgMe provides vinylsilanes in good yields.The method is also applicable to the allylsilane synthesis from allylic sulfides and ethers.

Full text of DOI:10.1016/S0040-4039(00)84475-5

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