ORGANIC SYNTHESIS WITH REAGENTS DERIVED FROM 3R3SiMgMe AND MnCl2

DOI: 10.1016/S0040-4020(01)86672-2

Source and publish data:

Tetrahedron p. 4277 - 4292 (1988)

Update date:2022-08-03

Topics:

Authors:

Fugami, Keigo

Hibino, Jun-ichi

Nakatsukasa, Shigeki

Matsubara, Seijiro

Oshima, Koichiro

et al. et al.

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Article abstract of DOI:10.1016/S0040-4020(01)86672-2

Synthetically useful reactions mediated by reagents derived from 3 equiv. of R3SiMgMe and MnCl2 are disclosed. (1) The manganese species reacted with terminal acetylenes to give 1,2-disilylated 1-alkenes.Mono- and bis(trimethylsilyl)acetylenes gave tri- a

Full text of DOI:10.1016/S0040-4020(01)86672-2

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