Tetrahedron p. 4277 - 4292 (1988)
Update date:2022-08-03
Topics:
Fugami, Keigo
Hibino, Jun-ichi
Nakatsukasa, Shigeki
Matsubara, Seijiro
Oshima, Koichiro
et al.
Synthetically useful reactions mediated by reagents derived from 3 equiv. of R3SiMgMe and MnCl2 are disclosed. (1) The manganese species reacted with terminal acetylenes to give 1,2-disilylated 1-alkenes.Mono- and bis(trimethylsilyl)acetylenes gave tri- a
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