Bisplatinum(II) Salts: Evidence for the Formation of a Five-co-ordinate Bis-halogenoplatinum(II) Cation

DOI: 10.1039/DT9870000705

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 705 - 708 (1987)

Update date:2022-08-03

Topics:

Authors:

Grossel, Martin C.

Moulding, Roger P.

Seddon, Kenneth R.

Walker, Fiona J.

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Article abstract of DOI:10.1039/DT9870000705

The salts X2 (X = Cl, Br, I, PF6, or BPh4; dppm = Ph2PCH2PPh2) have been studied in solution by 1H, 31P, and 195Pt n.m.r. spectroscopy and by conductivity measurements.The halide salts are believed to form the five-co-ordinate cation ⁺ in solution.

Full text of DOI:10.1039/DT9870000705

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