LEWIS ACID CATALYZED REARRANGEMENTS OF STUCTURALLY RELATED α,β-UNSATURATED EPOXY KETONES AND OXIMES. A COMPLEMENTARY APPROACH TO THE SYNTHESIS OF ISOMERIC 1,4-DIKETOSPIRO ALKANES.

DOI: 10.1016/S0040-4039(00)84850-9

Source and publish data:

Tetrahedron Letters p. 3565 - 3568 (1986)

Update date:2022-08-04

Topics:

Authors:

Bach, Robert D.

Tubergen, Mark W.

Klix, Russel C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)84850-9

Lewis acid catalyzed rearrangement of α,β-epoxy oximes proceeds by oxirane cleavage α to the oxime moiety with an attendant pinacol type alkyl migration to the resonance stabilized carbenium ion at Cα affording a 1,3-diketo-monoxime.

Full text of DOI:10.1016/S0040-4039(00)84850-9

Products guided by the article

Product name:7-Hydroxy-spiro[4.5]dec-7-en-6-one

Cas No:108573-05-3

R&D Labs maybe for 108573-05-3

MINS GROUP CO.,LIMITED

Contact:18669908765

Address:Zibo City, Shandong Province, P.R.China
Antimex Chemical Limied

website:http://www.antimex.com

Contact:0086-21-50563169

Address:Room1027,No.Jinyu Road,Pudong
Changde Yungang Biotechnology Co., Ltd

website:http://www.cdyg.com

Contact:+86-736-7391178

Address:Qiaonan Industrial Park, Changde City, Hunan Province
Shanghai Forever Synthesis Co.,Ltd.

Contact:021-61124658

Address:Zhoukang Road,Pudong New District,Shanghai,China
Lian Xing Chemical Co.,Ltd.

Contact:0792-8228321

Address:10TH Floor No.121 binjiang Road Xunyang District

Relevant to this article

An efficient synthesis of 2-(2,2-difluoroethoxy)-6-trifluoromethyl-n-(5,8- dimethoxy-1,2,4-triazolo[1,5-c]pyrimidine-2-yl) benzenesulfonamide: Penoxsulam

Doi:10.3184/174751913X13619014318618
(2013)
Cardiotonic agents. 6. Synthesis and inotropic activity of 2,4-dihydro-5-[4-(1H-imidazol-1-yl)phenyl]-3H-pyrazol-3-ones: Ring-contracted analogues of imazodan (CI-914)

Doi:10.1021/jm00393a007
(1987)
Screening helix-threading peptides for RNA binding using a thiazole orange displacement assay

Doi:10.1016/j.bmc.2008.08.066
(2008)
Doi:10.1021/ja01598a069
(1956)
Synthesis of 4-(N,N-dialkylamino)benzyltriphenylphosphonium iodides from hydroxymethyltriphenylphosphonium iodide and N,N-dialkylaniline

Doi:10.1080/00397910802238783
(2008)
Fluoride Ion Mediated Peterson of Bis(trimethylsilyl)methylimines: a Novel Synthesis of 2-Aza-1,3-dienes and N-Vinyl-β-lactams

Doi:10.1039/c39890000072
(1989)

Article Doi