Chemistry of Heterocyclic Compounds p. 980 - 982 (1986)
Update date:2022-07-29
Topics:
Soldatenkov, A. T.
Bagdadi, M. V.
Fedorov, V. O.
Prostakov, N. S.
Nucleophilic substitution (phenylation with phenyl lithium) of 1H-1-methylindeno<2,1-b>pyridine occurred at the C(2) and C(4) positions, and electrophilic substitution (methylation and benzylation with halogen derivatives) at C(9).Reduction of the starting anhydrobases gave 1-methyl-1,2,3,9a-tetrahydro-1-azafluorene, and pyrolysis gave 1-azafluorene and 1-azafluorenone.
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