
Tetrahedron Letters p. 5409 - 5412 (1986)
Update date:2022-08-04
Topics:
Sakakibara, Tohru
Yoshino, Kohji
Iizuka, Hiroyuki
Ishido, Yoshiharu
Chlorination of 3-nitro-D-glucal derivative in ethylene oxide and in hexamethylene oxide is described and compared with those in p-dioxane, tetrahydrofuran, tetrahydropyran, trimethylene oxide, and diethyl ether; a fairly good correlation is observed between the yield of D-glucopyranosyl chloride (4) and methyl cation affinity.
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(1987)