CHLORINATION OF 1,5-ANHYDRO-3-NITRO-1-ENITOL DERIVATIVE IN VARIOUS ETHERS AND ITS MNDO STUDY

DOI: 10.1016/S0040-4039(00)85224-7

Source and publish data:

Tetrahedron Letters p. 5409 - 5412 (1986)

Update date:2022-08-04

Topics:

Authors:

Sakakibara, Tohru

Yoshino, Kohji

Iizuka, Hiroyuki

Ishido, Yoshiharu

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Article abstract of DOI:10.1016/S0040-4039(00)85224-7

Chlorination of 3-nitro-D-glucal derivative in ethylene oxide and in hexamethylene oxide is described and compared with those in p-dioxane, tetrahydrofuran, tetrahydropyran, trimethylene oxide, and diethyl ether; a fairly good correlation is observed between the yield of D-glucopyranosyl chloride (4) and methyl cation affinity.

Full text of DOI:10.1016/S0040-4039(00)85224-7

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