Chemistry of 1,2-Thiaphosphole 2-Sulfides. III. Cycloaddition Reactions with Some Acetylenic Dienophiles and Generation of Phosphorin 1-Sulfides

DOI: 10.1246/bcsj.59.2047

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2047 - 2049 (1986)

Update date:2022-09-26

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Authors:

Tanaka, Hideyuki

Motoki, Shinichi

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Article abstract of DOI:10.1246/bcsj.59.2047

1,2-Thiaphosphole 2-sulfides reacted with dimethyl acetylenedicarboxylate or phenylacetylene to afford 1-phosphabarrelene 1-sulfides (1-phosphabicyclo<2.2.2>octa-2,5,7-triene 1-sulfides) via phosphorin 1-sulfides.

Full text of DOI:10.1246/bcsj.59.2047

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