THE 1,3-MIGRATION OF PHOSPHORUS FROM OXYGEN TO CARBON: A NEW SYNTHESIS OF β-KETOPHOSPHONATES FROM ENOL PHOSPHATES

DOI: 10.1016/S0040-4039(00)94248-5

Source and publish data:

Tetrahedron Letters p. 4265 - 4268 (1986)

Update date:2022-08-03

Topics:

Authors:

Hammond, Gerald B.

Calogeropoulou, Theodora

Wiemer, David F.

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Article abstract of DOI:10.1016/S0040-4039(00)94248-5

Enol phosphates, readily prepared from ketone enolates and dialkyl phosphorochloridate, can be converted to the analogous β-ketophosphonates by treatment with straong base.

Full text of DOI:10.1016/S0040-4039(00)94248-5

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