Tetrahedron p. 3245 - 3250 (1986)
Update date:2022-09-26
Topics:
Naef, Ferdinand
Decorzant, Rene
α-Damascone (1), a rose fragrance chemical, was synthesized by an allylmagnesium chloride addition to ketene 7 as key step.When the same ketene 7 was reduced by two different aluminium hydride reagents, α-cyclocitral was obtained.The presumed intermediates, enolates II and III, were first trapped as silyl enol ethers and then hydrolyzed with D2O to give the expected α-monodeuterated carbonyl compounds.Mixed aluminium hydride reduction of ketenes is recommended as a facile entry into the chemistry of aldehyde enolates.
View MoreBeijing Cooperate Pharmaceutical Co.,Ltd
Contact:86-01060279497
Address:No.507,Building 4,Tianhua Street, Biomedicine industrial Base
PUYANG WANQUAN CHEMICAL CO.,LTD.
Contact:86-393-5388048
Address:Shihua Rd,Puyang city, Henan province, CN
Contact:0755-28995781
Address:shenzhen
Shanghai Korey Pharm Co.,Ltd.(expird)
Contact:021-61840961 021-61840962
Address:No.157,Zhuguang Rd, Qingpu, Shanghai, China
Beijing Stable Chemcial Co.ltd
Contact:86-10-63785052
Address:A1301 Technological Edifice. No.4 FuFeng Road,FengTai District, Beijing. China
Doi:10.1246/cl.1986.1849
(1986)Doi:10.1016/S0040-4039(00)85134-5
(1986)Doi:10.1016/j.polymer.2015.05.032
(2015)Doi:10.1021/jm800854e
(2008)Doi:10.1246/cl.2008.1046
(2008)Doi:10.1016/j.tetlet.2008.07.102
(2008)
