Tetrahedron p. 3245 - 3250 (1986)
Update date:2022-09-26
Topics:
Naef, Ferdinand
Decorzant, Rene
α-Damascone (1), a rose fragrance chemical, was synthesized by an allylmagnesium chloride addition to ketene 7 as key step.When the same ketene 7 was reduced by two different aluminium hydride reagents, α-cyclocitral was obtained.The presumed intermediates, enolates II and III, were first trapped as silyl enol ethers and then hydrolyzed with D2O to give the expected α-monodeuterated carbonyl compounds.Mixed aluminium hydride reduction of ketenes is recommended as a facile entry into the chemistry of aldehyde enolates.
View MoreNingbo Inno Pharmchem Co., Ltd.
Contact:86-574-87319282
Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA
Daicel Chiral Technologies (China)CO.,LTD
Contact:021-5046-0086*8
Address:Part C, FL 5, the 16th Building, No. 69, XiYa Road, WaiGaoQiao Free Trade Zone, Shanghai, 200131, P.R.China
Hebei Think-Do Environment Co., Ltd
website:http://www.thinkdo-environment.com
Contact:0311-86510809-
Address:No 6, Shilian Middle Street, Circular Chemical Industry Park
WUHU HUAHAI BIOLOGY ENGINEERING CO LTD
Contact:+86-553-3836920
Address:7/F NO.82 LAODONG ROAD WUHU CHINA
Contact:86-511-85210668 0511-85210668, 85210818, 85210898
Address:Yihai Garden E-902,NO.99 Daxi RD., Zhenjiang Jiiangsu ,China
Doi:10.1246/cl.1986.1849
(1986)Doi:10.1016/S0040-4039(00)85134-5
(1986)Doi:10.1016/j.polymer.2015.05.032
(2015)Doi:10.1021/jm800854e
(2008)Doi:10.1246/cl.2008.1046
(2008)Doi:10.1016/j.tetlet.2008.07.102
(2008)
