Ring Expansion in the Addition of Dichlorocarbene to 2,5-Dihydro-1H-phosphole 1-Oxides

DOI: 10.1021/jo00227a008

Source and publish data:

Journal of Organic Chemistry p. 3983 - 3986 (1987)

Update date:2022-08-05

Topics:

Authors:

Keglevich, Gyoergy

Petnehazy, Imre

Miklos, Peter

Almasy, Attila

Toth, Gabor

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00227a008

While the addition of dichlorocarbene to 2,5-dihydro-3-methyl-1H-phosphole 1-oxides (1a-d) carried out under phase-transfer catalytic conditions gave 6,6-dichloro-1-methyl-3-phosphabicyclo<3.1.0>hexane 1-oxides (2a-d), the 3,4-dimethyl-1-phenyl analogue (

Full text of DOI:10.1021/jo00227a008

Products guided by the article

Product name:1H-Phosphepin, 4,5-dichloro-3,6-dimethyl-1-phenyl-, 1-oxide

Cas No:109011-58-7

R&D Labs maybe for 109011-58-7

Qingdao XinYongAn Chemicals Co., Ltd

Contact:+86-532-81107967

Address:Chengyang dual-port industrial park by the sea，Qingdao
Nanjing Legend Pharmaceutical & Chemical Co., Ltd.

Contact:+86-25-83767696

Address:14-7 Zhongshan Lu Guluo District, Nanjing
Nantong LiKai Chemical Co.,Ltd

Contact:+86-513-89068669

Address:Jincheng Science Park
Daqing E-shine Chemical Co.,LTD

Contact:0086-024-31285112

Address:Hongweiyuan area, Ranghulu district
Joyochem Co., Ltd.

website:https://sdjingyuan.lookchem.com/

Contact:86-531-82687998

Address:Factory Building 11, Jinan Comprehensive free trade zone, Shandong, China

Relevant to this article

Doi:10.1002/ardp.19572901011
(1957)
A dicationic, podand-like, ionic liquid water system accelerated copper-catalyzed azide-alkyne click reaction

Doi:10.1016/j.cclet.2014.09.005
(2014)
Complementary iron(II)-catalyzed oxidative transformations of allenes with different oxidants

Doi:10.1002/anie.201510006
(2016)
Rhodium(III)-catalyzed arene and alkene C-H bond functionalization leading to indoles and pyrroles

Doi:10.1021/ja1082624
(2010)
In situ generated bulky palladium hydride complexes as catalysts for the efficient isomerization of olefins. Selective transformation of terminal alkenes to 2-alkenes

Doi:10.1021/ja9108424
(2010)
An Asymmetric Vinylogous Michael Cascade of Silyl Glyoximide, Vinyl Grignard, and Nitroalkenes via Long Range Stereoinduction

Doi:10.1021/acs.joc.5b02693
(2016)

Article Doi