Ring Expansion in the Addition of Dichlorocarbene to 2,5-Dihydro-1H-phosphole 1-Oxides

DOI: 10.1021/jo00227a008

Source and publish data:

Journal of Organic Chemistry p. 3983 - 3986 (1987)

Update date:2022-08-05

Topics:

Authors:

Keglevich, Gyoergy

Petnehazy, Imre

Miklos, Peter

Almasy, Attila

Toth, Gabor

et al. et al.

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Article abstract of DOI:10.1021/jo00227a008

While the addition of dichlorocarbene to 2,5-dihydro-3-methyl-1H-phosphole 1-oxides (1a-d) carried out under phase-transfer catalytic conditions gave 6,6-dichloro-1-methyl-3-phosphabicyclo<3.1.0>hexane 1-oxides (2a-d), the 3,4-dimethyl-1-phenyl analogue (

Full text of DOI:10.1021/jo00227a008

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