Photochemistry of 9-Diazo-3,6-diazafluorene: Through-Space or Through-Bond Transmission of Electronic Effects

DOI: 10.1021/jo00227a006

Source and publish data:

Journal of Organic Chemistry p. 3975 - 3979 (1987)

Update date:2022-08-04

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Authors:

Li, Yu-Zhuo

Schuster, Gary B.

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Article abstract of DOI:10.1021/jo00227a006

Irradiation of (-diazo-3,6-diazafluorene (36DAF) in hydrocarbon solvents gives 3,6-diazafluorenylidene (36FL) by loss of N2 and the isomeric diazirine 1 by valence tautomerization.The chemical and physical properties of 36DAF are compared with those of th

Full text of DOI:10.1021/jo00227a006

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