Synthesis p. 1067 - 1070 (1986)
Update date:2022-09-26
Topics:
Barua, Nabin C.
Schmidt, Richard R.
Direct lithiation of β-ethylthio- and β-phenylthioacrylic acid affords β-lithiopropionate equivalents.The usefulness of these reagents is demonstrated in a convenient synthesis of α,β-unsaturated δ-lactones and their transformation into the corresponding saturated δ-lactones.The required reaction with epoxides as electrophiles was promoted by addition of boron trifluoride-ether.
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Doi:10.1039/b811401c
(2008)Doi:10.1039/b813454e
(2008)Doi:10.1016/S0040-4039(00)85258-2
(1986)Doi:10.1111/j.1348-0421.2002.tb02663.x
(1904)Doi:10.1055/s-1986-31867
(1986)Doi:10.3390/molecules20023354
(2015)