Photochemical Conversion of 7,7-Diphenyl-2,3-epoxybicycloheptan-6-ones into a 2-Oxabicyclohexan-3-one

DOI: 10.1039/c39840000640

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 640 (1984)

Update date:2022-08-05

Topics:

Authors:

Davies, H. Geoff

Roberts, Stanley M.

Wakefield, Basil J.

Winders, John A.

Williams, David J.

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Article abstract of DOI:10.1039/c39840000640

Photolysis of the epoxide (3) or (5) gave the strained lactone (4) in 40 - 50percent yield; the bicyclic lactone (4) gave the functionalised cyclobutane (6) on treatment with acidic methanol, the structure of which was confirmed by X-ray analysis.

Full text of DOI:10.1039/c39840000640

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Product name:2-endo-bromo-3-exo-hydroxy-7,7-diphenylbicyclo<3.2.0>heptan-6-one

Cas No:109584-23-8

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