PALLADIUM-CATALYZED REDUCTION OF PROPARGYLIC ACETATES WITH SmI2. A MILD AND CONVENIENT METHOD FOR THE PREPARATION OF ALLENES

DOI: 10.1016/S0040-4039(00)85178-3

Source and publish data:

Tetrahedron Letters p. 5237 - 5240 (1986)

Update date:2022-08-02

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Authors:

Tabuchi, Takanori

Inanaga, Junji

Yamaguchi, Masaru

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Article abstract of DOI:10.1016/S0040-4039(00)85178-3

A highly regioselective reduction of propargylic acetates has been attained by using SmI2 and catalytic Pd(0) in the presence of 2,4-dimethyl-3-pentanol affording various types of allenes in high yields.

Full text of DOI:10.1016/S0040-4039(00)85178-3

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