Methyl Trideuteriomethyl (E)-(α-Bromoarylidene)malonates: Simple Stereochemical Probes in Nucleophilic Vinylic Substitution near the Retention/Stereoconvergence Borderline

DOI: 10.1021/ja00256a024

Source and publish data:

Journal of the American Chemical Society p. 6698 - 6710 (1987)

Update date:2022-08-04

Topics:

Authors:

Rappoport, Zvi

Gazit, Aviv

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00256a024

Methyl trideuteriomethyl (E)-(α-bromo-p-methyl- and -p-nitrobenzylidene)malonates (4 and 5) were prepared.These electrophilic bromo olefins are activated to vinylic substitution by ywo chemically identical but isotopically distinguishable CO2Me groups.The

Full text of DOI:10.1021/ja00256a024

Products guided by the article

Product name:C₁₉H₁₅⁽²⁾H₃O₅

Cas No:110242-67-6

R&D Labs maybe for 110242-67-6

U-Chemo Holding Co.,Limited

website:http://www.u-chemo.com

Contact:+86-21-61558312

Address:Dong Fang Road,
Jiacheng-Chem Enterprises Limited(expird)

Contact:86-571-86711508

Address:19 Floor, CIBC Holley International Building, No. 198,Wuxing Road, Hangzhou, China,310020
Changzhou Ansciep Chemical Co.,Ltd.

Contact:+86 519 8630 5871

Address:A-710 Boan International, 8 East Guangdian Road,Wujin,Changzhou
Changzhou Foreign Trade Corp

Contact:+86-519-86623222

Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China
NINGBO PANGS CHEM INT’L CO.,LTD.

Contact:+86-574-27666845

Address:FLOOR 21,BUILDING NO.11,XIN TIAN DI,NO.689 SHI JI ROAD,NINGBO CHINA

Relevant to this article

Homo- and heteroleptic zinc aminophenolates as initiators for lactide polymerization

Doi:10.1039/b808882a
(2008)
Synthesis, characterization and structure-activity relationship analysis of novel depsides as potential antibacterials

Doi:10.1016/j.ejmech.2008.04.019
(2009)
Comparison of preparation methods of N-arylsulfinyl-1,4-benzoquinone monoimines

Doi:10.1134/s1070428008020085
(2008)
An efficient one-pot synthetic method for 2,4-disubstituted 7-arylpyrido [4,3-d]pyrimidines from 2,4-disubstituted 6-(arylethynyl)pyrimidine-5- carbaldehydes and tert-butylamine

Doi:10.1055/s-0028-1083500
(2008)
Doi:10.1002/hlca.19560390535
()
Doi:10.1021/ja01596a049
(1956)

Article Doi