Angewandte Chemie - International Edition p. 9079 - 9083 (2008)
Update date:2022-08-04
Topics:
Green, Shaun P.
Jones, Cameron
Stasch, Andreas
(Figure Presented) A bit of a stretch! A series of stable Lewis base adducts of a dimeric magnesium(I) complex has been prepared and shown to possess exceptionally long Mg-Mg bonds. Theoretical studies on model compounds suggest the elongations of these bonds are low-energy processes. The structures of the magnesium(I) adducts are compared with those of related magnesium(II) hydride complexes (see picture; Mg pink, N blue, O red, H green).
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