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3-METHYL-γ-BUTYROLACTONE AS A SOURCE OF 2-METHYL-3-HYDROXYKETONES AND 2-METHYL-1,3-DIOLS: A SYNTHESIS OF THE C19-C27 FRAGMENT OF RIFAMYCIN S BY LINEAR ITERATION

DOI: 10.1016/S0040-4039(00)95405-4

Source and publish data:

Tetrahedron Letters p. 1725 - 1728 (1987)

Update date:2022-08-05

Topics: 3-Methyl-γ-butyrolactone  

Authors:

Ziegler, Frederick E.Ziegler, Frederick E.

Kneisley, AlyssaKneisley, Alyssa

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Article abstract of DOI:10.1016/S0040-4039(00)95405-4

3-Methyl-γ-butyrolactone has been employed as a source of 2-methyl-3-hydroxyketones after functioning as a template for the preparation of enantiomerically pure propionate chains.This method is exemplified by the preparation of the C19-C27 propionate frag

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Full text of DOI:10.1016/S0040-4039(00)95405-4

Products guided by the article

Product name:tert-Butyl-{(R)-2-[(4S,5S,6S)-6-((E)-(S)-1,4-dimethyl-pent-2-enyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-propoxy}-diphenyl-silane

Cas No:110455-57-7

110455-57-7

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