Tetrahedron Letters p. 391 - 394 (1987)
Update date:2022-09-26
Topics:
Mohr, Peter
Tamm, Christoph
V(5+)-Catalyzed t-butylhydroperoxide epoxidation of (Z)-5-hydroxy-2-alkenylsilanes 4 exhibit good to excellent erythro selectivity.The resulting epoxides undergo fragmentation to afford 1,3-diols 8, albeit in low chemical yield.
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