Journal of Organic Chemistry p. 5548 - 5560 (1987)
Update date:2022-07-29
Topics: Regioselectivity Pyrolysis Isomerization Substituent Effects Stereoselectivity Cycloaddition Thermal Rearrangement Computational Chemistry Conformational Analysis Activation Energy Spectroscopic Characterization Concerted Mechanism Kinetic Control Thermodynamic Control Tautomerization Retro-Diels-Alder Reaction Intramolecular Diels-Alder Reaction Dienophile Diene Rearrangement Reaction Pericyclic reaction Transition state Rate-determining step HOMO-LUMO interaction
Eddaif, Abdelhamid
Laurent, Andre
Mison, Pierre
Pellissier, Nicole
Carrupt, Pierre-Alain
Vogel, Pierre
The syntheses of methyl- and phenyl-substituted 2H-pyrroles 8 bearing a but-3-enyl or pent-4-enyl side chain are reported.The thermolyses of 8 yielded tricyclic derivatives with the 2-azabicyclo<2.2.1>hept-2-ene moiety resulting from the intramolecular Di
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