Journal of the Chemical Society. Chemical communications p. 559 - 560 (1987)
Update date:2022-08-04
Topics: Transition metal
Fischer, Helmut
Tiriliomis, Athanassios
Gerbing, Ulrike
Huber, Brigitte
Mueller, Gerhard
Pentacarbonyl-chromium- and -tungsten-co-ordinated thio- and seleno-aldehydes and selenoketones, respectively, react with 1-diethylaminoprop-1-yne via regiospecific <2+2> cycloaddition and stereospecific electrocyclic ring-opening to give metal-co-ordinated thio- and seleno-acrylamide derivatives which can be cleaved almost quantitatively from the metal by CO (100 atm).
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Doi:10.1016/S0022-1139(00)82001-1
(1987)Doi:10.1016/S0040-4039(00)95732-0
(1987)Doi:10.1016/S0040-4020(01)88108-4
(1986)Doi:10.1021/jm060955d
(2006)Doi:10.1021/ja01678a005
(1925)Doi:10.1021/ja809491b
(2009)
