Fluorinated Tertiary Thio- and Selenoethers from the Reaction of Sulfenyl or Selenenyl Chloride with Perfluoropropene Dimers in the Presence of Alkali Fluoride

DOI: 10.1246/bcsj.60.4471

Source and publish data:

Bulletin of the Chemical Society of Japan p. 4471 - 4473 (1987)

Update date:2022-08-03

Topics:

Authors:

Suzuki, Hitomi

Satake, Hiroshi

Uno, Hidemitsu

Shimizu, Hiroaki

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Article abstract of DOI:10.1246/bcsj.60.4471

Perfluoro(1,1-dimethylbutanide) anion generated from hexafluoropropene dimers and alkali fluorides in dry N,N-dimethylformamide, reacts with arenesulfenyl or areneselenenyl chloride to give the corresponding aryl perfluoro(1,1-dimethylbutyl) sulfides or selenides in low to good yields.

Full text of DOI:10.1246/bcsj.60.4471

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