Bulletin of the Chemical Society of Japan p. 2665 - 2666 (1987)
Update date:2022-08-04
Topics:
Yamamoto, Yasuhiro
Takahashi, Katsuo
Yamazaki, Hiroshi
The electrochemical behavior of PdCl2(RNC)2 (1) has been investigated in acetonitrile at Pt and Hg electrodes.The cyclic voltammogram of 1 showed a reduction wave at ca -1.2 V, corresponding to a two-electron transfer.Coulometric reduction of 1 at the Pt electrode gave a binuclear complex, Pd2Cl2(RNC)4 (2).A similar reaction at the Hg electrode gave 2 in a relatively low yield.A Pt electrode was superior to a Hg one in the electrochemical synthesis of 2.The polarogram of 1 at a Hg electrode suggested a CE mechanism of the electrode ration.
Contact:886 2 2541 0022
Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.
Zibo Jujin Chemical Industry Co., Ltd.（Dongming Jujin Chemical Industry Co., Ltd. ）
Contact:+86-533-2975022
Address:No.99 Shanquan Road, Zhangdian District
Contact:86-532-68629711 13780605697
Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
Shanggao Ruiya Fine Chemicals Co., Ltd
Contact:+86-795-2592103
Address:Xingguang Nanlu,Shanggao County Industry Park
Winchem Industrial Co. Ltd.(expird)
Contact:86-574-83851061 86-574-87083208
Address:Room 905, No.3 Building,East Business Center, 456 Xingning Road, Ningbo City,China
Doi:10.1515/znb-1962-0705
()Doi:10.1021/jacs.5b11318
(2016)Doi:10.1016/j.mencom.2008.03.020
(2008)Doi:10.1016/j.ejmech.2010.05.024
(2010)Doi:10.1016/j.tetlet.2010.11.093
(2011)Doi:10.1021/jo00018a006
(1991)
