Bulletin of the Chemical Society of Japan p. 2665 - 2666 (1987)
Update date:2022-08-04
Topics:
Yamamoto, Yasuhiro
Takahashi, Katsuo
Yamazaki, Hiroshi
The electrochemical behavior of PdCl2(RNC)2 (1) has been investigated in acetonitrile at Pt and Hg electrodes.The cyclic voltammogram of 1 showed a reduction wave at ca -1.2 V, corresponding to a two-electron transfer.Coulometric reduction of 1 at the Pt electrode gave a binuclear complex, Pd2Cl2(RNC)4 (2).A similar reaction at the Hg electrode gave 2 in a relatively low yield.A Pt electrode was superior to a Hg one in the electrochemical synthesis of 2.The polarogram of 1 at a Hg electrode suggested a CE mechanism of the electrode ration.
Yangling Ciyuan biotech Co., Ltd.
Contact:86-15802970736
Address:2-1804, International Park Mansion, No.2, South Fengdeng Road, Lianhu District
Shanghai Puda Chemical Co.,Ltd
Contact:+86+571+56565965
Address:10F Haiyue Building,Danfeng Road,Binjiang District,Hangzhou,China
Changyi Xinxing Technology Development Co., Ltd.
Contact:0086-510-86651065(Time Zone:8),86651656
Address:94 Yingbinxilu WestRoad, Huangtu Town, Jiangyin City, Jiangsu, China
Shanghai Xinda Pharmaceuticals Co., Ltd.
Contact:86-21-33692333-8008
Address:999 Linxian Road, Jinshan Industrial Park, Shanghai, China
Contact:0086-29-89196322
Address:North of the Fifth Keji Road, Hi-Tech Industrial Zone, Xi'an City, Shaanxi Province, China
Doi:10.1515/znb-1962-0705
()Doi:10.1021/jacs.5b11318
(2016)Doi:10.1016/j.mencom.2008.03.020
(2008)Doi:10.1016/j.ejmech.2010.05.024
(2010)Doi:10.1016/j.tetlet.2010.11.093
(2011)Doi:10.1021/jo00018a006
(1991)
