The reactions of the Betti base with 1,3-dicarbonyl compounds

DOI: 10.3184/030823408X282686

Source and publish data:

Journal of Chemical Research p. 3 - 5 (2008)

Update date:2022-08-05

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Authors:

Wen, Jian-Ming

Lin, Cui-Pan

Li, Jing-Hua

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Article abstract of DOI:10.3184/030823408X282686

Reaction of the Betti base 1-(α-aminobenzyl)-2-naphthol with 1,3-dicarbonyl compounds at room temperature in CH₃OH in the presence of p-toluenesulfonic acid leads to the corresponding enamino carbonyl products 3, in high yield and with high chemical purity. Among them, 3b was proven to be an enamine with cis-configuration by single crystal X-ray diffraction analysis.

Full text of DOI:10.3184/030823408X282686

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