STEREOCHEMISTRY OF THE SN2' DISPLACEMENT OF CHIRAL 1,3-DISUBSTITUTED BROMOALLENES TO FORM CHIRAL ACETYLENES

DOI: 10.1016/0040-4039(84)80007-6

Source and publish data:

Tetrahedron Letters p. 3059 - 3062 (1984)

Update date:2022-08-03

Topics:

Authors:

Corey, E. J.

Boaz, Neil W.

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Article abstract of DOI:10.1016/0040-4039(84)80007-6

Optically active 1,3-disubstituted bromoallenes react with a variety of cuprate reagents preferentially is an S_N2' fashion with very high anti selectivity.

Full text of DOI:10.1016/0040-4039(84)80007-6

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