ASYMMETRIC SYNTHESIS OF HETEROORGANIC ANALOGS OF NATURAL COMPOUNDS. 4. DIASTEREO- AND ENANTIOSELECTIVE SYNTHESIS OF (2S,3S)-4,4,4-TRIFLUOROTHREONINE AND (2S,3S)-β-PERFLUOROALKYLSERINES

Article abstract of DOI:10.1007/BF00961234

Perfluorinated aliphatic aldehydes react with the Ni(II) complex of the glycine Schiff base with (S)-2-benzophenone in the presence of MeONa to give (2S,3S)-perfluoroalkylserines, while alkanals react to form (2R,3S)-diastereomers