Journal of the Chemical Society. Chemical communications p. 104 - 106 (1987)
Update date:2022-08-05
Topics:
Baldwin, Jack E.
Adlington, Robert M.
Kang, Tae Won
Lee, Eun
Schofield, Christopher J.
Homolytic reductive debromination of a 2β-bromomethyl penam by triphenyltin hydride provides, via ring expansion of the derived 2β-methyl radical, the corresponding cepham system; a similar process may explain the biosynthetic ring expansion of penicillin
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