Di-l-menthyl (Acetoxymethylene)malonate, a New Chiral Dienophile: Enantioselective Route to Carbocyclic Analogues of C-Nucleoside

DOI: 10.1021/jo00236a057

Source and publish data:

Journal of Organic Chemistry p. 226 - 227 (1988)

Update date:2022-09-26

Topics:

Authors:

Katagiri, Nobuya

Haneda, Toru

Hayasaka, Etsuko

Watanabe, Nobuhisa

Kaneko, Chikara

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Article abstract of DOI:10.1021/jo00236a057

Titanium tetrachloride promoted Diels-Alder reaction of new chiral dienophile, di-l-menthyl (acetoxymethylene)malonate, with cyclopentadiene not only proceeds with high diastereofacial selectivity but also provides an efficient enantioselective synthetic

Full text of DOI:10.1021/jo00236a057

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