FLUORINATED CARBOHYDRATES AS POTENTIAL PLASMA MEMBRANE MODIFIERS AND INHIBITORS. SYNTHESIS OF 2-ACETAMIDO-2,6-DIDEOXY-6-FLUORO-D-GALACTOSE

Article abstract of DOI:10.1016/0008-6215(87)80199-4

Reaction of benzyl 2-acetamido-3,4-di-O-benzyl-2-deoxy-6-O-mesyl-α-D-galactopyranoside with cesium fluoride gave benzyl 2-acetamido-3,6-anhydro-4-O-benzyl-2-deoxy-α-D-galactopyranoside instead of the desired 6-fluoro derivative.Acetonation of benzyl 2-ace