Synthesis and asymmetric reactivity of enantiomerically pure cyclopentadienylmetal complexes derived from the chiral pool

DOI: 10.1021/om00094a015

Source and publish data:

Organometallics p. 883 - 892 (1988)

Update date:2022-08-03

Topics:

Authors:

Halterman, Ronald L.

Vollhardt, K. Peter C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00094a015

Starting from pulegone, camphor, and tartrate, three chiral cyclopentadienes were prepared efficiently. Metalation with Co₂(CO)⁸ and TiCl₃ resulted in new chiral and enantiomerically pure substituted cyclopentadienyldicarb

Full text of DOI:10.1021/om00094a015

Products guided by the article

Product name:(η-5-((1R,2R,5R)-5-methyl-2-(2-phenyl-2-propyl)cyclohex-1-yl)cyclopentadienyl)dicarbonylcobalt

Cas No:112505-34-7

R&D Labs maybe for 112505-34-7

Luna Chemicals Co.,Ltd.

Contact:+86-570-4336358

Address:No.87 Building,Tianqian,Sidu Town
Hangzhou Pharma & Chem Co.,Ltd.

Contact:+86-571-87040515

Address:No,139Qingchun Rd
Shanghai Topchem Co., LTD

website:http://www.shtopchem.com/

Contact:0086-0576-87776998

Address:room no 1608,xuhui business building yude road,xujiahui street, xuhui district
Tangshan Moneide Trading Co., Ltd.

Contact:+86-315-8309571

Address:2-7-420 Jidong Building Materials Commercial Center, Tangshan, Hebei, 064000 China
HENAN NEW BLUE CHEMICAL CO.,LTD

website:http://www.newbluechem.com

Contact:86-371-55170693/55170694

Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China

Relevant to this article

THE EFFECT OF STYRENE α-SUBSTITUENTS ON THE REGIOCHEMISTRY OF <2+2> CYCLOADDITIONS WITH DIFLUOROALLENE.

Doi:10.1016/S0040-4039(01)81023-6
(1987)
Doi:10.1016/S0020-1693(00)82013-7
(1988)
Synthesis of Complex Tertiary Glycolates by Enantioconvergent Arylation of Stereochemically Labile α-Keto Esters

Doi:10.1021/jacs.7b00943
(2017)
Concise and highly stereoselective syntheses of D-fagomine and 2-epi-fagomine

Doi:10.1016/j.tetlet.2016.02.046
(2016)
General synthetic approach to 4-substituted 2,3-dihydrofuro[2,3-b]pyridines and 5-substituted 3,4-dihydro-2H-pyrano[2,3-b]pyridines

Doi:10.1055/s-0028-1087485
(2009)
2,3-BIS(DIPHENYLPHOSPHINYL)-1,3-BUTADIENE VIA A DOUBLE <2,3>-SIGMATROPIC REARRANGEMENT. A REINVESTIGATION OF THE REACTION OF 2-BUTYNE-1,4-DIOL WITH CHLORODIPHENYLPHOSPHINE

Doi:10.1016/S0040-4039(00)95917-3
(1987)

Article Doi