Synthesis and asymmetric reactivity of enantiomerically pure cyclopentadienylmetal complexes derived from the chiral pool

DOI: 10.1021/om00094a015

Source and publish data:

Organometallics p. 883 - 892 (1988)

Update date:2022-08-03

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Authors:

Halterman, Ronald L.

Vollhardt, K. Peter C.

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Article abstract of DOI:10.1021/om00094a015

Starting from pulegone, camphor, and tartrate, three chiral cyclopentadienes were prepared efficiently. Metalation with Co₂(CO)⁸ and TiCl₃ resulted in new chiral and enantiomerically pure substituted cyclopentadienyldicarb

Full text of DOI:10.1021/om00094a015

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