Conjugate Addition of Acetylides to Complexes of Type > (M=Cr, Mo, or W): Crystal Structure of >formed by the Base-catalysed Isomerization of CPh>>

DOI: 10.1039/DT9880000089

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 89 - 92 (1988)

Update date:2022-07-31

Topics:

Authors:

Hassan, Fatma S. M.

Shaw, Bernard L.

Thornton-Pett, Mark

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9880000089

Although treatment of > with Li(C<*>)CPh resulted in no conjugate addition, in the presence of Me2NCH2CH2NMe2 smooth addition occurred to give CPh>> (1c).Similar additions were effected with the corresponding complexes of Cr and other acetylides, Li(C<*>CR) where R=C6H4Me-p, Me, Prⁿ, or Buⁿ, underwent addition.Treatment of CPh>> with KOBu^t in PrⁱOH gave the dienephosphine comples > (2a); the p-tolylacetylide complex > was also prepared.Crystals of compound (2a) are monoclinic, space group P2₁/c with a=988.4(3), b=1069.7(2), c=3233.7(4) pm, β=94.73(2) deg, and Z=2; final R=0.0334 and R'=0,0316 for 3929 observed reflexions.Hydrogen-1 and 31P-<1H> n.m.r. and i.r. data are given.

Full text of DOI:10.1039/DT9880000089

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{1,1-bis(diphenylphosphino)hept-3-yne-P,P'}-tetracarbonylmolybdenum

Cas No:112536-79-5

R&D Labs maybe for 112536-79-5

Lyan Limited

Contact:86-021-52418058

Address:8/F, Building 6, Guiping Road No.333, Shanghai, 200233, China
suzhou chukai pharmateach co,.ltd

Contact:86-512-88812511

Address:Building 3, Wujiang Scientific Innovation Park, 2358 Changan Rd, Wujiang 215200, Jiangsu Province, P. R. China
KINHENG CHEMICAL(SHANGHAI)CO., LTD.

Contact:+8621-60490170

Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.
Xi'an caijing Opto-Electrical Science & Technology Co., LTD

Contact:+86-29-88294447

Address:NO.168 Zhangba Rd. East, Xi'an, P.R.China
Shijiazhuang Yunxuan Im&Export Co.,Ltd.

Contact:+86-311-83037514

Address:No.6 Hongbin Road

Relevant to this article

A NEW ROUTE TO 3-HETEROARYLINDOLES

Doi:10.1016/S0040-4020(01)90049-3
(1987)
SYNTHESIS OF ISOCHROMANS VIA THE TITANIUM TETRACHLORIDE ASSISTED CYCLIZATION OF ACETALS OF PHENETHYL ALCOHOLS

Doi:10.1016/S0040-4039(00)96149-5
(1987)
Heteroarylamide smoothened inhibitors: Discovery of N-[2,4-dimethyl-5-(1-methylimidazol-4-yl)phenyl]-4-(2-pyridylmethoxy)benzamide (AZD8542) and N-[5-(1H-imidazol-2-yl)-2,4-dimethyl-phenyl]-4-(2- pyridylmethoxy)benzamide (AZD7254)

Doi:10.1016/j.bmc.2019.115227
(2020)
Synthesis of 1-methylbenzimidazoles from carbonitriles

Doi:10.1055/s-0028-1087383
(2009)
Two-dimensional hydrogen-bonded networks in two novel glycoluril derivatives

Doi:10.1107/S0108270107067108
(2008)
Reactivity of electrogenerated N-heterocyclic carbenes in room-temperature ionic liquids. Cyclization to 2-azetidinone ring via C-3/C-4 bond formation

Doi:10.1002/adsc.200800049
(2008)

Article Doi