Tetrahedron Letters p. 707 - 710 (1988)
Update date:2022-08-04
Topics: Catalysts Degradation Carboxylic Acids Free radical reactions
Patel, Vinod F.
Pattenden, Gerald
Arylmethyl- and allyl-acylcobalt salophens, undergo facile C-Co bond homolysis and in situ decarbonylation, producing new (alkyl) radical centres which can be intercepted with oxygen, nitrogen, halogen, sulphur and selenium containing radical trapping agents, leading to functionalised nor-alkanes (Scheme).
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