FREE RADICAL REACTIONS INITIATED BY ORGANOCOBALT COMPLEXES. A NEW METHOD FOR THE DEGRADATION OF CARBOXYLIC ACIDS TO FUNCTIONALISED NOR-ALKANES VIA ACYLCOBALT SALOPHEN INTERMEDIATES.

DOI: 10.1016/S0040-4039(00)80190-2

Source and publish data:

Tetrahedron Letters p. 707 - 710 (1988)

Update date:2022-08-04

Topics: Catalysts Degradation Carboxylic Acids Free radical reactions

Authors:

Patel, Vinod F.

Pattenden, Gerald

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Article abstract of DOI:10.1016/S0040-4039(00)80190-2

Arylmethyl- and allyl-acylcobalt salophens, undergo facile C-Co bond homolysis and in situ decarbonylation, producing new (alkyl) radical centres which can be intercepted with oxygen, nitrogen, halogen, sulphur and selenium containing radical trapping agents, leading to functionalised nor-alkanes (Scheme).

Full text of DOI:10.1016/S0040-4039(00)80190-2

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